| 66 | 0 | 54 |
| 下载次数 | 被引频次 | 阅读次数 |
拐子湖坳陷为银额盆地铀成矿潜力突出的大型二级构造单元,开展地下水铀溶解-沉淀水文地球化学特征研究,对砂岩型铀成矿远景区圈定与找矿预测具有重要意义。系统揭示拐子湖坳陷苏红图组成矿期与近代地下水的铀溶解-沉淀规律,定量厘定其成矿水文地球化学边界条件。以野外地质-水文地质调查与样品采集为基础,采用水-岩体系浸泡试验与PHREEQC水文地球化学模拟,定量刻画铀溶解-沉淀特征。研究区近代地下水pH介于7.7~10.5之间、 Eh介于-100~136 mV之间,铀含量介于0.05~12.16μg·L-1之间;成矿期古地下水pH介于5.85~9.63之间、Eh介于-250~92 mV之间,铀含量介于0.02~0.616 mg·L-1之间。苏红图组近代地下水沥青铀矿沉淀Eh临界值介于-214.2~-41.83 mV之间,铀浓度临界值介于1.52~2 241 mg·L-1之间;成矿期铀溶解-沉淀Eh临界值介于-95.50~167.29 mV之间、铀浓度临界值介于0.1~463.37μg·L-1之间。YESY-120采样点靠近铀沉淀临界条件;ZKC9剖面孔深介于450~550 m之间段具备优越的砂岩型铀成矿水文地球化学环境。以上认识可以为铀溶解沉淀的定量判别提供科学依据,对该区铀成矿远景区预测具有重要的现实意义。
Abstract:The Guaizihu depression is a major secondary structural unit with prominent uranium metallogenic potential in the Yingen-Ejin basin. This study investigated hydrogeochemical characteristics of uranium dissolution and precipitation in groundwater. This paper systematically revealed the laws of uranium dissolution and precipitation in both ore-forming period paleo-groundwater and modern groundwater of the Suhongtu Formation in the Guaizihu depression,and quantitatively defines the hydrogeochemical boundary conditions for uranium mineralization. Based on field geological and hydrogeological surveys as well as sample collection,with water-rock interaction leaching tests and PHREEQC hydrogeochemical simulation,we quantitatively characterize the features of uranium dissolution and precipitation. In the study area,modern groundwater shows a pH range of 7.7~10.5,an Eh range of-100~136 mV,and uranium content of 0.05~12.16 μg·L-1. Paleo-groundwater during the oreforming period had a pH range of 5.85~9.63,an Eh range of-250~92 mV,and uranium content of 0.02~0.616 mg·L-1. For modern groundwater of the Suhongtu Formation,the critical Eh values for pitchblende precipitation are-214.2~-41.83 mV,and the critical uranium concentrations are 1.52~2 241 mg·L-1. During the ore-forming period,the critical Eh values for uranium dissolution and precipitation were-95.50~167.29 mV,and the critical uranium concentrations were 0.1~463.37 μg·L-1. The sampling site YESY-120 is close to the critical conditions for uranium precipitation. The depth interval of 450~550 m in section ZKC9 presents favorable hydrogeochemical conditions for sandstone-type uranium mineralization. The above findings supply scientific references for quantitative discrimination of uranium dissolution and precipitation. It provides key support for delineating prospective areas and conducting prospecting prediction of sandstone-type uranium deposits.
1张成勇,秦彦伟,邱林飞,等.银额盆地中新生代断陷湖盆中原生红色沉积与后生红色改造的区分标志与分布规律[J].世界核地质科学,2026,43(2):199-214.Zhang Chengyong,Qin Yanwei,Qiu Linfei,et al.Distinguishing criteria and distribution patterns of original red sedimentation and epiginetic red alteration in the Mesozoic-Cenozoic faulted down Yingen-Ejin basin[J].World Nuclear Geoscience,2026,43(2):199-214(in Chinese).
2杨晓冉.我国铀矿勘查获突破性进展[N].中国能源报,2023-07-31(008).Yang Xiaoran.Breakthrough progress in uranium exploration in China[N].China Energy News,2023-07-31(008)(in Chinese).
3岳淑娟.二连盆地额仁淖尔-巴彦乌拉地区砂岩型铀成矿水文地质条件研究[D].北京:中国地质大学,2011.Yue Shujuan.A study on hydrogeological conditions of sandstone-type uranium mineralization in ErennoerBayanwula area in Erlian basin[D].Beijing:China University of Geosciences,2011(in Chinese).
4闫德志,刘人和,杨松林,等.砂岩型铀矿成矿要素及成矿模式[J].地质论评,2025,71(S1):174-176.Yan Dezhi,Liu Renhe,Yang Songlin,et al.Metallogenic elements and metallogenic model of sandstone type uranium deposit[J].Geological Review,2025,71(S1):174-176(in Chinese).
5禹宝利,张振强.松辽盆地南部钱家店凹陷姚家组含水层水成铀矿作用分析[J].铀矿冶,2022,41(4):346-351.Yu Baoli,Zhang Zhenqiang.Analysis on hydrogenic uranium mineralization of Yaojia formation aquifer in Qianjiadian depression of South Songliao basin[J].Uranium Mining and Metallurgy,2022,41(4):346-351(in Chinese).
6何忧.伊犁盆地砂岩型铀矿的水文地球化学成矿机理[D].武汉:中国地质大学(武汉),2019.He You.Hydrogeochemical metallogenic mechanism of sandstone-type uranium deposits in Yili basin[D].Wuhan:China University of Geosciences,2019(in Chinese).
7王志明,李森,肖丰,等.某砂岩型铀矿床成矿水文地质条件研究[J].中国核科技报告,1997:183-194.Wang Zhiming,Li Sen,Xiao Feng,et al.Study on hydrogeological conditions for mineralization of some sandstone type uranium deposit[J].China Nuclear Science and Technology Report,1997:183-194(in Chinese).
8陈法正.鄂尔多斯盆地北部古水文地质条件与铀成矿前景分析[J].铀矿地质,2002,18(5):287-294.Chen Fazheng.Analysis of paleohydrogeological conditions and uranium metallogenesis northern part of Ordos basin[J].Uranium Geology,2002,18(5):287-294(in Chinese).
9王震亮,陈荷立.鄂尔多斯盆地中部上古生界古流体动力分析[J].沉积学报,1998,12(4):105-108.Wang Zhenliang,Chen Heli.A Paleohydrodynamic analysis of the Upper Paleozoic group in middle Ordos basin[J].Acta Sedimentologica Sinica,1998,12(4):105-108(in Chinese).
10刘金辉,王联社,朱捌.潮水盆地铀成矿水文地球化学研究[J].东华理工大学学报(自然科学版),2005,28(2):101-106.Liu Jinhui,Wang Lianshe,Zhu Ba.The study on uranium ore-forming hydrogeochemistry of Chaoshui basin[J].Journal of East China University of Technology(Natural Science),2005,28(2):101-106(in Chinese).
11张广辉,王成渭.浅析库车前陆盆地水文地质条件与铀成矿作用[J].世界核地质科学,2008,25(2):86-93+123.Zhang Guanghui,Wang Chengwei.Preliminary discussion on hydrogeological conditions and uranium metallogenesis in Kuche foreland basin[J].World Nuclear Geoscience,2008,25(2):86-93+123(in Chinese).
12齐清林,莫帮洪,刘秀林,等.龙潭向斜铀成矿水文地质条件浅析[J].四川地质学报,2015,35(3):412-416.Qi Qinglin,Mo Banghong,Liu Xiulin,et al.Hydrogeological conditions for uranium ore-formation in the Longtan synclinal axis[J].Acta Geologica Sichuan,2015,35(3):412-416(in Chinese).
13任晓平,刘晓敏,彭瑞强,等.二连盆地巴彦乌拉铀矿床水文地质条件与铀成矿关系[J].世界核地质科学,2022,39(3):554-560.Ren Xiaoping,Liu Xiaomin,Peng Ruiqiang,et al.The relationship between hydrogeological conditions and uranium mineralization of Bayanwula uranium deposit in Erlian basin[J].World Nuclear Geoscience,2022,39(3):554-560(in Chinese).
14李晓红,李盛富,任满船,等.卡姆斯特地区水文地质条件与铀成矿关系[J].世界核地质科学,2023,40(1):51-57.Li Xiaohong,Li Shengfu,Ren Manchuan,et al.Relationship between hydrogeological conditions and uranium mineralization in Kamusite area[J].World Nuclear Geoscience,2023,40(1):51-57(in Chinese).
15吴晓智,何登发,陈晓明,等.银根-额济纳旗盆地石油地质特征与资源潜力[J].地质科学,2020,55(2):404-419.Wu Xiaozhi,He Dengfa,Chen Xiaoming,et al.Petroleum geological characteristics and resource potential of Yingen-Ejinaqi basin[J].Chinese Journal of Geology,2020,55(2):404-419(in Chinese).
16刘武生,李伟涛,杨喆,等.巴音戈壁盆地塔木素铀矿床成矿作用新认识——热水白云石化-渗出叠加-渗入改造模式[J].铀矿地质,2023,39(6):1002-1018.Liu Wusheng,Li Weitao,Yang Zhe,et al.Hydrothermal dolomitization-exudation superposition-infiltration transformation model for uranium metallogenesis of Tamusu deposit in Bayin Gobi basin[J].Uranium Geology,2023,39(6):1002-1018(in Chinese).
17李伟涛,刘武生,贾立城,等.银额盆地苏红图地区铀矿化特征与成矿作用[J].世界核地质科学,2025,42(5):943-957.Li Weitao,Liu Wusheng,Jia Licheng,et al.Uranium mineralization and metallogenesis of Suhongtu area in Yingen-Ejin basin[J].World Nuclear Geoscience,2025,42(5):943-957(in Chinese).
18李子颖,秦明宽,郭庆银,等.渗出砂岩型铀矿成矿预测与找矿标志[J].铀矿地质,2024,40(1):1-15.Li Ziying,Qin Mingkuan,Guo Qingyin,et al.Metallogenic prediction and exploration indication of exudative sandstonetype uranium deposit[J].Uranium Geology,2024,40(1):1-15(in Chinese).
19李伟涛,刘武生,纪宏伟,等.银额盆地赛尔亥那地区铀矿化特征及成因研究[J].铀矿地质,2024,40(1):143-156.Li Weitao,Liu Wusheng,Ji Hongwei,et al.Study on the characteristics and genesis of uranium mineralization in Saierhaina area in Yin’e basin[J].Uranium Geology,2024,40(1):143-156(in Chinese).
20刘政国,秦彦伟,李伟涛,等.银额盆地测老庙铀矿床成矿特征及成矿模式[J].世界核地质科学,2025,42(5):974-987.Liu Zhengguo,Qin Yanwei,Li Weitao,et al.Mineralization characteristics and model of Celaomiao uranium deposit in Yingen-Ejin basin[J].World Nuclear Geoscience,2025,42(5):974-987(in Chinese).
21杨喆,刘武生,牛霆,等.银额盆地居延海坳陷早白垩世断陷期沉积演化特征及其对砂岩型铀矿形成的影响[J].世界核地质科学,2023,40(2):162-173.Yang Zhe,Liu Wusheng,Niu Ting,et al.Early Cretaceous sedimentary evolution of Juyanhai depression in Yin’e basin and its influence on the formation of sandstone-type uranium deposits[J].World Nuclear Geoscience,2023,40(2):162-173(in Chinese).
22陈启林,卫平生,杨占龙.银根-额济纳盆地构造演化与油气勘探方向[J].石油实验地质,2006,28(4):311-315.Chen Qilin,Wei Pingsheng,Yang Zhanlong.Tectonic evolution and petroleum prospection in the YingenEjina basin[J].Petroleum Geology&Experiment 2006,28(4):311-315(in Chinese).
23杨润泽,王宏语,樊太亮,等.银额盆地拐子湖凹陷构造特征及其对古地貌演化的控制[J].大庆石油地质与开发,2020,39(6):39-51.Yang Runze,Wang Hongyu,Fan Tailiang,et al.Structural characteristics and their controlling effects over the paleogeomorphic evolution for Guaizihu sag in Yin’e basin[J].Petroleum Geology&Oilfield Development in Daqing,2020,39(6):39-51(in Chinese).
24张泽均.拐子湖凹陷中生代构造样式特征[J].化工管理,2021(7):80-81.Zhang Zejun.Characteristics of mesozoic structural styles in the Guaizihu depression[J].Chemical Engineering Management,2021(7):80-81(in Chinese).
25 Paradis C J,Hoss K N,Meurer C E,et al.Elucidating mobilization mechanisms of uranium during recharge of river water to contaminated groundwater[J].Journal of Contaminant Hydrology,2022,251:104076.
26高永华.基于PHREEQC的地下水化学演化反向模拟[J].地下水,2023,45(1):50-52.Gao Yonghua.Reverse simulation of groundwater chemical evolution based on PHREEQC[J].Groundwater,2023,45(1):50-52(in Chinese).
27徐乐昌.地下水模拟常用软件介绍[J].铀矿冶,2002,21(1):33-38.Xu Lechang.Introduction to common software products modeling groundwater[J].Uranium Mining and Metallurgy,2002,21(1):33-38(in Chinese).
28 Parkhurst D L,Appelo C A J.User’s guide to PHREEQC(Version 2):A computer program for speciation,batchreaction,one-dimensional transport,and inverse geochemical calculations[R/OL].Denver:U.S.Geological Survey,1999.
29韩积斌,许建新,安朝,等.利用PHREEQC模拟CO2对盐湖卤水中U的影响[J].盐湖研究,2015,23(3):23-28.Han Jibin,Xu Jianxin,An Chao,et al.Effect of the uranium in the brine during the CO2 leakage:a theoritical simulation from PHREEQC[J].Journal of Salt Lake Research,2015,23(3):23-28(in Chinese).
30刘金辉,史维浚,孙占学.反应条件指数及其与饱和指数的关系初步探讨[J].地学前缘,2005,12(增刊1):124-126.Liu Jinhui,Shi Weijun,Sun Zhanxue.A primary study of reaction condition index and its relationship with saturation index[J].Earth Science Frontiers,2005,12(Sup.1):124-126(in Chinese).
31刘苏鹏,刘金辉,刘武生,等.银额盆地居延海坳陷苦泉沟组砂岩水文地球化学与铀溶解沉淀特征[J].世界核地质科学,2025,42(5):1003-1019.Liu Supeng,Liu Jinhui,Liu Wusheng,et al.Hydrogeochemistry and uranium dissolutionprecipitation characteristics of sandstone in Kuquangou formation of Juyanhai depression,Yingen-Ejin basin[J].World Nuclear Geoscience,2025,42(5):1003-1019(in Chinese).
32刘金辉,孙占学.确定砂岩型铀矿体定位新方法——水岩体系Eh-p H法[J].吉林大学学报(地球科学版),2004,34(1):44-48.Liu Jinhui,Sun Zhanxue.A new method to determine the position of sandstone type uranium ore-body:waterrock system Eh-p H method[J].Journal of Jilin University(Earth Science Edition),2004,34(1):44-48(in Chinese).
基本信息:
中图分类号:P641.3;P619.14
引用信息:
[1]廖宏亮,刘金辉,刘武生,等.银额盆地拐子湖坳陷苏红图组地下水铀溶解-沉淀水文地球化学特征[J].世界核地质科学,2026,43(04):749-761.
基金信息:
核技术研发项目(编号:地H2401)资助~~
2026-05-28
2026-05-28
2026-05-28